What's the difference between arsine and hydrogen?

Arsine


Definition:

  • (n.) A compound of arsenic and hydrogen, AsH3, a colorless and exceedingly poisonous gas, having an odor like garlic; arseniureted hydrogen.

Example Sentences:

  • (1) Higher concentrations of methemoglobin in animals in the 2.500 ppm exposure group (measured after 90 days of exposure) indicated that the rate of oxidation of heme (ferrous to ferric) increased due to exposure to arsine gas.
  • (2) Arsine and in general airborne arsenic compounds show the main cancer promoting characteristics.
  • (3) In order to examine possible species differences in response to arsine exposure, multiple inhalation studies consisting of acute (1-day), subacute (14- and 28-day), and subchronic (90-day) exposures to this agent were conducted using three different species of rodents.
  • (4) Fetuses weighed more than in the control group but other endpoints of developmental toxicity were not affected by arsine exposure.
  • (5) While the clinical picture suggested arsine or stibine poisoning, preliminary investigation of the plant revealed no obvious source of arsenic, antimony, or hydrogen gas.
  • (6) Hematocrit values at 24 hr after exposure decreased linearly with increasing arsine concentration in the range 5 to 26 ppmv; the hematocrit of the 26-ppmv group reached 10.5% at 24 hr, compared to 48.4% for control mice.
  • (7) A 1 g sample is wet washed in a 16 x 150 mm 10 mL volumetric test tube on a programmed heating block with nitric, sulfuric, and perchloric acids at up to 310 degrees C. After treatment with hydrochloric acid and potassium iodide, arsenic is reduced by sodium borohydride to arsine in a simplified continuous flow manifold.
  • (8) To examine these, we exposed male and female mice to 0.000, 0.025, 0.500 and 2.500 ppm arsine gas for 6 h a day, 5 days a week during a 90-day period.
  • (9) Concern about semiconductor workers prompted an in-depth study of arsine at the National Institute of Environmental Health Sciences to determine the hematopoietic effects of prolonged exposure to this gas.
  • (10) Effects on other organs were not observed, suggesting that the hematopoietic system is the primary target for arsine.
  • (11) At least three times more arsine than dimethylarsine was produced in soil incubated with dimethylarsinate.
  • (12) The number of live fetuses, mean fetal body weight, and percentages of resorptions or malformations per litter were not affected by arsine exposure.
  • (13) In most situations where arsine can be formed if antimony is present.
  • (14) After 5, 15, and 90 days of exposure, blood was collected and routine hematologic profiles were performed to document the effects of arsine gas on peripheral blood.
  • (15) The National Institute for Occupational Safety and Health (NIOSH) recommends that appropriate workpractices be implemented to reduce the risk of worker exposure to arsine (AsH3) gas.
  • (16) We drew a conclusion that TM-As is far less an toxic than arsine, most probably due to its in vivo conversion to TMAO.
  • (17) A series of eight neutral technetium(II)-99m complexes of general formula tr-[99mTcIID2X2]0, where D represents a chelating ditertary phosphine or arsine ligand and X represents a halide or pseudohalide ligand, has been prepared and characterized by HPLC comparisons to the known 99Tc analogs.
  • (18) This recommendation is based on several reports of worker exposure to arsine resulting in severe toxic effects or death.
  • (19) Among these arsines, dimethylarsine was mutagenic in WP2 (wild-type; Exc+Rec+) and WP2uvrA (uvrA-; Exc-Rec+), while trimethylarsine was not.
  • (20) An accuracy investigation, initiated because of conflicting analytical data on the arsenic content for some 24 drinkinig water locations in the Mojave Desert, revealed that interference with the evolution of arsine in the American Public Health Association silver diethyldithiocarbamate method caused either color enhancement or arsine suppression.

Hydrogen


Definition:

  • (n.) A gaseous element, colorless, tasteless, and odorless, the lightest known substance, being fourteen and a half times lighter than air (hence its use in filling balloons), and over eleven thousand times lighter than water. It is very abundant, being an ingredient of water and of many other substances, especially those of animal or vegetable origin. It may by produced in many ways, but is chiefly obtained by the action of acids (as sulphuric) on metals, as zinc, iron, etc. It is very inflammable, and is an ingredient of coal gas and water gas. It is standard of chemical equivalents or combining weights, and also of valence, being the typical monad. Symbol H. Atomic weight 1.

Example Sentences:

  • (1) The hypothesis that proteins are critical targets in free radical mediated cytolysis was tested using U937 mononuclear phagocytes as targets and iron together with hydrogen peroxide to generate radicals.
  • (2) It has been conformed that catalase from bovine liver eliminates only the pro R hydrogen atom from ethanol.
  • (3) We investigated the possible contribution made by oropharyngeal microfloral fermentation of ingested carbohydrate to the generation of the early, transient exhaled breath hydrogen rise seen after carbohydrate ingestion.
  • (4) Hydrogen isotope effects on these mutants indicate that MotA catalyzes proton transfer.
  • (5) Excessive accumulation of hydrogen ions in the brain may play a pivotal role in initiating the necrosis seen in infarction and following hyperglycemic augmentation of ischemic brain damage.
  • (6) Studies were conducted in isolated, buffer-perfused rat lungs to determine if prostaglandin (PG) E1 attenuated pulmonary edema provoked by hydrogen peroxide (H2O2).
  • (7) All N and O atoms except N(3) and O(4') participate in a three-dimensional hydrogen-bonding system.
  • (8) Both adiphenine.HCl and proadifen.HCl form more stable complexes, suggesting that hydrogen bonding to the carbonyl oxygen by the hydroxyl-group on the rim of the CD ring could be an important contributor to the complexation.
  • (9) Control mutant S38N has stability essentially the same as that of wild-type lysozyme but hydrogen bonding similar to that of the stabilizing mutant S38D.
  • (10) High intensity ultrasound also enhances the heterogeneous catalysis of alkene hydrogenation by Ni powders.
  • (11) An atmosphere of hydrogen eliminates this inhibition in the hydrogenase-containing T. foetus but not in E. invadens which lacks the enzyme.
  • (12) Vanadate-dependent oxidation of either pyridine nucleotide was inhibited by the addition of either superoxide dismutase or catalase, indicating that both superoxide and hydrogen peroxide may be intermediates in the process.
  • (13) Our findings suggest that (a) the inclusion of a liquid meal provides a reproducible method of measuring orocaecal transit using the lactulose hydrogen breath test, (b) rapid small bowel transit in thyrotoxicosis may be one factor in the diarrhoea which is a feature of the disease and (c) if altered gut transit is the cause of sluggish bowel habit in hypothyroidism, delay in the colon, and not small bowel, is likely to be responsible.
  • (14) Stepwise hydrogenation of metal tetradehydrocorrin salts (10 double bonds) yields a series of macrocycles containing 9, 8, 7, 6 and 5 double bonds and conditions necessary to obtain corrins have been established.
  • (15) For dipeptides containing the amino terminal residues glycine, alanine and phenylalanine, abstraction of the hydrogen from the carbon adjacent to the peptide nitrogen was the major process leading to the spin-adducts.
  • (16) (7) The first-order radical transformation rates are independent of the (initial) concentration of N3 or peptide and unaffected by urea (as a modifier of hydrogen bond structures).
  • (17) Intermolecular contacts occur in both oligomers in the minor groove: in the B form through twisted guanine-guanine hydrogen bonding, and in the Z form through base-base stacking and the water network.
  • (18) Equilibrium-partitioning measurements indicate that the relative affinities of different probes for PC-rich vesicles, in competition with HODMA or DOTAP vesicles, increase with increasing hydrogen-bonding capacity of the probe headgroup in the order PC less than N,N-dimethyl PE less than N-methyl PE less than PE approximately phosphatidyl-2-amino-1-propanol.
  • (19) When tissue metabolism was irreversibly inhibited by exposure to formaldehyde, hydrogen ion concentration and pCO2 were significantly decreased in the mucosal side of the chamber compared with the viable gall bladder.
  • (20) Based on the refined atomic coordinates of the tRNAphe in the orthorhombic crystal, on the recent advances in the distance dependence of the ring-current magnetic field effects and on the adopted values for the isolated hydrogen-bonded NH resonances, a computed spectrum consisting of 23 protons was constructed.