What's the difference between cation and phosphonium?

Cation


Definition:

  • (n.) An electro-positive substance, which in electro-decomposition is evolved at the cathode; -- opposed to anion.

Example Sentences:

  • (1) The actions of the polyvalent cationic dye Ruthenium Red and the enzyme neuraminidase were studied at the frog neuromuscular junction.
  • (2) Interaction of viable macrophages with cationic particles at 37 degrees C resulted in their "internalization" within vesicles and coated pits and a closer apposition between many segments of plasmalemma than with neutral or anionic substances.
  • (3) On the other hand, the hydrophilic reagents, 1-ethyl-3-[3-(dimethylamino)-propyl]carbodiimide and N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline, did not affect organic cation transport.
  • (4) Kup is a separate K+ uptake system with relatively little discrimination in the transport of the cations K+, Rb+, and Cs+.
  • (5) To selectively stain polyanionic macromolecules of growth plate cartilage and to prevent artifacts induced by aqueous fixation, proximal tibial growth plates were excised from rats, slam-frozen, and freeze-substituted in 100% methanol containing the cationic dye Alcian blue.
  • (6) In general, enzyme activity was strongly reduced by heavy metal inorganic cations; less strongly by organometallic cations, some anions, and certain pesticides; and weakly inhibited by light metal cations and organometallic and organic compounds.
  • (7) Conflicting reports exist on the postprandial response of serum cationic trypsin like immunoreactivity (SCTLI).
  • (8) Frequent measurement of serum cation and appropriate replacement are recommended when high dose Cisplatin containing regimen is used in chemotherapy of neoplasms.
  • (9) Binding is inhibited by divalent and trivalent cations (Cd2+ and La3+ being most potent) and other calcium channel drugs (1,4 dihydropyridines, phenylalkylamines, benzothiazepines).
  • (10) The planar 7H-pyridocarbazole cations form stacks approximately parallel to b. Interactions between stacks occur by weak van der Waals forces.
  • (11) Bio-Rex 70, a carboxylic acid cation exchanger, is studied as a biological ion-exchanger resin model for cellular cytoplasm.
  • (12) 45Calcium has been used to compare the kinetics for the transport and bioaccumulation of this regulatory cation in keratinocyte cultures of a kindred with HPS (i.e., one HPS homozygote, one HPS obligate heterozygote, one normal family member, and healthy adult controls).
  • (13) Although GTP most potently inhibited [125I]beta h-endorphin binding in the presence of sodium, inhibition of [125I]beta h-endorphin binding by GTP was also observed in the presence of the monovalent cations lithium and potassium, but not the divalent cations magnesium, calcium, or manganese.
  • (14) The fungicidal activity of six rabbit neutrophil cationic peptides (NP) against resting (dormant) spores, preincubated (swollen) spores, and hyphae of Aspergillus fumigatus and Rhizopus oryzae was examined.
  • (15) No significant relationship was found between these urinary cations and blood pressure.
  • (16) Cation concentrations were determined in a stratified subsample (n = 89) of the study group.
  • (17) The cation leak identified in this manner is not prelytic, and it is fully reversible.
  • (18) Na+ could not be replaced for growth by any other cations or substances.
  • (19) When the concentration of Ca2+ in the medium was raised to 10 mM was the only extracellular divalent cation present, the depolarization in response to A23187 was increased to 11-8 mV.
  • (20) Mn2+ had dual effects, stimulating the ECP release in the absence of Mg2+ and Ca2+, and inhibiting the release in the presence of these cations.

Phosphonium


Definition:

  • (n.) The hypothetical radical PH4, analogous to ammonium, and regarded as the nucleus of certain derivatives of phosphine.

Example Sentences:

  • (1) It is also found to be sensitive to inhibition by tetraphenyl phosphonium, magnesium, and ruthenium red.
  • (2) The accumulation of lipophilic cation radiolabeled tri-phenylmethyl phosphonium (TPMP+) was utilized to determine the resting membrane potential across the plasma membrane psi.
  • (3) The state of the skeleton was studied in 62 patients with otosclerosis to investigate diagnostic potentialities of 99mTc-phosphonium, of them in 34 patients the diagnosis was confirmed at operation.
  • (4) The stimulation of AIB transport following ouabain removal was largely abolished by a proton ionophore (1799), a lipophilic cation (tetraphenyl-phosphonium), or ouabain.
  • (5) These compounds were prepared by modification of the Corey prostaglandin synthesis utilizing as a key step condensation of known hemiacetals with the ylide derived from the requisite substituted phosphonium salts.
  • (6) The fatty acid composition of the resulting phosphonium phosphatidylcholine is similar to that of phosphatidylcholine.
  • (7) The phosphonium ions used here promote desensitization of the receptor, as judged by the binding rate of the fluorescent agonist NBDA-C5-acylcholine or alpha-bungarotoxin.
  • (8) The procedure starts with readily available aldehydes or ketones and the common intermediate p-bromobenzyltriphenyl-phosphonium bromide in a Wittig reaction and proceeds in good yield through p-bromostyrene and p-cyanostyrene intermediates.
  • (9) An electrode sensitive to tetraphenyl phosphonium (TPP+) was applied to monitor the changes in the membrane potential of the ciliate Blepharisma japonicum during the process of cell elongation.
  • (10) Evidence consistent with the operation of a single efflux system for compounds such as phosphonium ions, phenanthridiniums and flavines is presented.
  • (11) Overshoot can be diminished but not suppressed by a proton-conducting uncoupler, carbonyl cyanide m chlorophenylhydrazone, (CCCP) and by a liposoluble cation, triphenyl-methyl phosphonium (TPMP+).
  • (12) The transmembrane potential, as measured from the equilibrium distribution of tritiated triphenylmethyl phosphonium and by using the fluorescent probe, Di-S-C3(5), is approximately -37 millivolts.
  • (13) The average membrane potential was estimated by measuring the uptake of [3H]tetraphenyl phosphonium ([3H]Ph4P+).
  • (14) Uptake of the lipophilic cation tetraphenyl phosphonium was largely abolished by addition of magainin A and PGLa showed synergism with respect to release of respiratory control.
  • (15) In the suspension of cytochrome oxidase proteoliposome the uptake of a cationic penetrant (tetraphenyl phosphonium cation) was found to be coupled with electron transfer via external cytochrome c. Electron transfer via intraproteoliposomal cytochrome c induced the uptake of anionic penetrants (tetraphenyl borate and phenyldicarbaundecaborane anions).
  • (16) As judged by the uptake of the voltage-sensitive probe [3H]triphenylmethyl phosphonium we observed a close correlation between conditions which inhibit virus infection and which cause depolarization of the cells.
  • (17) The rate of synthesis and degradation of phosphatidylcholine and of the phosphonium analogue are similar.
  • (18) Several radioiodinated iodopentenyl-trisubstituted phosphonium, arsonium, and ammonium iodides have been prepared and evaluated in rats to determine the effects of structural variations of the cations on myocardial uptake and retention.
  • (19) The activation energy for both the porphyrin and phosphonium cation induced conductance is more positive than that of the tetraphenylboride conductance.
  • (20) We have synthesized 20,20,20-trifluoroarachidonic acid by the cis-selective Wittig reaction of the C12-C20 fragment with phosphonium salt.

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