What's the difference between chromophore and spectral?

Chromophore


Definition:

  • (n.) Any chemical group or residue (as NO2; N2; or O2) which imparts some decided color to the compound of which it is an ingredient.

Example Sentences:

  • (1) F(420) is photolabile aerobically in neutral and basic solutions, whereas the acid-stable chromophore is not photolabile under these conditions.
  • (2) Theoretical computations are performed of the intercalative binding of the neocarzinostatin chromophore (NCS) with the double-stranded oligonucleotides d(CGCG)2, d(GCGC)2, d(TATA)2 and d(ATAT)2.
  • (3) The drug-picrate chromophores maximally absorb within the first minute of reaction (21 s for phenacemide, 45 s for cephalothin), after which the absorbances decrease.
  • (4) The chromophore of octopus rhodopsin is 11-cis retinal, linked via a protonated Schiff base to the protein backbone.
  • (5) These results suggest that the chromophore-protein interaction is significantly altered during the phototransformation of phytochrome.
  • (6) Their absorption spectra are at sufficiently long wavelength to be unobscured by cellular chromophores such as nucleotides and aromatic amin acids.
  • (7) Synthesis products have been identified, and three chromophores have been displayed by their n----II and II----II dichroic transitions.
  • (8) These surplus chromophores become esterified and are temporarily taken up by the pigment epithelium to be re-entered into the visual cycle as fast as they can be processed by the regenerative machinery of the rod outer segments.
  • (9) Utilizing the known atomic coordinates of the chromophores (Schirmer, T., Bode, W. and Huber, R. (1987) J. Mol.
  • (10) In spite of this relatively high value and unusual stability, a persulfide group, R-S-SH, seems to be the most likely structure for this chromophore.
  • (11) The chromophore was found in the 105,000xg supernatant and gave a reduced CO-difference spectrum with an absorption maximum of 448 nm.
  • (12) The only other fluorescent chromophore in that region of the spectrum has excitation and emission peaks at 328 and 460 nm, respectively.
  • (13) When the monomer was further dissociated into constituent subunits in strong alkali or at high concentrations of SDS, the CD spectrum disappeared almost completely, indicating loss of the asymmetric interactions of the chromophoric heme a with its immediate environments, consisting of the subunit assembly.
  • (14) Using these techniques we have also determined a conditional reduction potential of -0.156 V for the chromophore producing fatty acyl-CoA substrate beta-2-furylpropionyl-CoA.
  • (15) This effect is attributed to intercalation of the ellipticine chromophore.
  • (16) The bathochromic shift may be a consequence of a reduced exposure of the chromophore to the aqueous solvent.
  • (17) In exogenous photosensitization, the chemical agent (chromophore) is most often identified, reaching the skin either via topical contact or by systemic administration (drugs).
  • (18) Circular dichroism of these compounds allows us to assign the transition due to the amide chromophore.
  • (19) Fourier-transform infrared difference spectroscopy has been used to detect the vibrational modes in the chromophore and protein that change in position or intensity between rhodopsin and the photoproducts formed at low temperature (70 K), bathorhodopsin and isorhodopsin.
  • (20) The second chromophore exhibits spectral properties (lambda max = 360, 255 nm, pH 2) similar to that observed for 7,8-dihydropterin cations.

Spectral


Definition:

  • (a.) Of or pertaining to a specter; ghosty.
  • (a.) Of or pertaining to the spectrum; made by the spectrum; as, spectral colors; spectral analysis.

Example Sentences:

  • (1) Spectral analysis of spontaneous heart rate fluctuations, a powerful noninvasive tool for quantifying autonomic nervous system activity, was assessed in Xenopus Laevis, intact or spinalized, at different temperatures and by use of pharmacological tools.
  • (2) From these data it is possible to predict theoretically the apparent temperature difference as seen by an infrared scanner or radiometer with a detector of which the spectral detectivity, D (lambda), is known.
  • (3) Ultraviolet difference spectrophotometry indicates that the inactivated enzyme retains its capacity for binding the nucleotide substrates whereas the spectral perturbation characteristic of 3-phosphoglycerate binding is abolished in the modified enzyme.
  • (4) In scanning of more than 20 Hz frequency, the spectral pattern also reflected the characteristics of the cone system.
  • (5) The probable reaction mechanisms prevailing in both cases are discussed in accordance with the low and high resolution mass spectral data presented.
  • (6) Four types of behavior were observed with increasing stimulation level: 1) the two spectral parameters and conduction velocity both increased with stimulation in 15 experiments, 2) the two spectral parameters decreased and conduction velocity increased in 8 experiments, 3) the two spectral parameters and conduction velocity both decreased in 6 experiments, and 4) the two spectral parameters increased and conduction velocity decreased in 3 experiments.
  • (7) In the analysis of background fluorescence, the principal components were, as for the two-step technique, autofluorescence and propidium spectral overlap.
  • (8) Starting from the observation that the part above 6 Hz of the power spectrum of force tremor during isometric contractions can be related to the unfused twitches of motor units firing asynchronously, an attempt was made to study the usefulness of force tremor spectral analysis as a global descriptor of motoneurone pool activity.
  • (9) Spectral changes were observed before histologic changes were apparent.
  • (10) Approaches have been worked out for the determination of qualitative composition of the mixtures and spectral parameters.
  • (11) Their structures were deduced as 3-O-beta-D-glucopyranosyl (1----3)-alpha-L-rhamnopyranosyl (1----2)-alpha-L-arabinopyranosyl hederagenin 28-O-beta-D-glucopyranosyl (1----6)-beta-D-glucopyranosyl ester (VII) and 3-O-alpha-L-rhamnopyranosyl (1----3)-beta-D-glucopyranosyl (1----3)-alpha-L-rhamnopyranosyl (1----2)-alpha-L-arabinopyranosyl hederagenin 28-O-beta-glucopyranosyl (1----6)-beta-D-glucopyranosyl ester (VIII), based on spectral analysis and chemical evidences as well as results of 2D-HPTLC.
  • (12) The melting profile exhibited two transitions--one at about 35 degrees C and one above 50 degrees C. Our spectral data showed that helices I and II were stable during the first transition, and agreed with other data that helix III was the most likely helix to have melted.
  • (13) The pH dependence of this spectral change gave a sigmoidal curve fitted well to a theoretical curve of a cooperative release of two protons with a pK value of 7.5, indicating the existence of the acidic and alkaline forms of the ferrous CO enzyme.
  • (14) The respiratory functions of the oropharynx, larynx, and trachea of normal human fetuses in utero were explored by means of real-time, two-dimensional ultrasonography combined with color-flow and spectral Doppler analysis.
  • (15) The spectral interaction between Hoechst and chromomycin is quantified.
  • (16) RR spectra of fatty acyl-CoA and its complexes are consistent with the previous hypothesis that visible spectral shifts observed during formation of acetoacetyl-CoA and crotonyl-CoA complexes of fatty acyl-CoA dehydrogenase result from charge-transfer interactions in which the ground state is essentially nonbonding as opposed to interactions in which complete electron transfer occurs to form FAD semiquinone.
  • (17) 4, 669-679), on the other hand, operates only on a collection of spectral data to extract the common spectral components with their spectral weights.
  • (18) On the basis of spectral and chemical evidence, pedicularioside E and F were identified to be 1'-O-beta-D-(3-methoxy-4-hydroxy-beta-phenyl)-ethyl-6'-O-feruloyl- alpha-L-(2-acetyl)-rhamnosyl-(1----3')-4'-acetylglucopyranoside and shanzhisin methyl ester cellobioside, respectively.
  • (19) The reports of rod-dominated psychophysical spectral sensitivity from the deprived eye of monocularly lid-sutured (MD) monkeys are intriguing but difficult to reconcile with the absence of any reported deprivation effects in retina.
  • (20) Comparison of implant-user performance with the temporal-only data reported here can help determine whether the speech information available to the implant user consists of entirely temporal cues, or is augmented by spectral cues.

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