What's the difference between crystalline and semicrystalline?

Crystalline


Definition:

  • (a.) Consisting, or made, of crystal.
  • (a.) Formed by crystallization; like crystal in texture.
  • (a.) Imperfectly crystallized; as, granite is only crystalline, while quartz crystal is perfectly crystallized.
  • (a.) Fig.: Resembling crystal; pure; transparent; pellucid.
  • (n.) A crystalline substance.
  • (n.) See Aniline.

Example Sentences:

  • (1) In addition to the phase diagrams reported here for these two binary mixtures, a brief theoretical discussion is given of other possible phase diagrams that may be appropriate to other lipid mixtures with particular consideration given to the problem of crystalline phases of different structures and the possible occurrence of second-order phase transitions in these mixtures.
  • (2) In 0.17 M Na+(aq), tRNA(Phe) exists in its native conformation and the number of strong binding sites (Ka greater than or equal to 10(4)) was estimated to be 3-4 by titration experiments, in agreement with X-ray structural data for crystalline tRNA(Phe) (Jack et al., 1977).
  • (3) Electron microscopy revealed the presence of a hitherto unreported peculiar "pilovacuolar" inclusion in numerous mitochondria, composed of an electron dense pile or rod within a vacuole, while globular or crystalline inclusions were absent.
  • (4) The advantages of the incision through the pars plana ciliaris are (1) easier approach to the vitreous cavity, (2) preservation of the crystalline lens and an intact iris, and (3) circumvention of the corneal and chamber angle complications sometimes associated with the transcorneal approach.
  • (5) These two crystallins were compared with respect to their native molecular masses, subunit structures, peptide mapping and amino acid compositions in order to establish the identity of each crystallin.
  • (6) Freeze-dried mannitol preparations were shown to be of a crystalline nature.
  • (7) Antigenic properties of crystalline pepsin, trypsin and chymotrypsin were studied in 9 rabbits immunised with these enzymes.
  • (8) X-ray diffraction spectrum of 1:8 coprecipitate (COPPT) showed no crystalline structure of AD.
  • (9) However, significant differences in the formation and melting of the highly crystalline phase were evident between the two polar headgroup stereoisomers.
  • (10) Degradation studies of the crystalline antibiotic, m.p.
  • (11) Crystalline derivatives of the amino sugar i. e. methyleremosaminide and methyl-N,O-acetyleremosaminide (alpha- and beta-anomers) were prepared.
  • (12) A systematic structural comparison of several carp gamma-crystallins with high methionine contents was made by the secondary-structure prediction together with computer model-building based on the established X-ray structure of calf gamma-II crystallin.
  • (13) The lens cell-free system synthesizes in addition to the crystallins, polypeptides which co-electrophorese with lens plasma membrane protein components.
  • (14) Arrhenius plots of the leakage rates showed breaks in the 20-25 degrees C temperature range, which correspond to the gel-liquid crystalline phase transition of the target liposomes.
  • (15) These results suggest that ATP modulates the functional behavior of alpha-crystallin.
  • (16) Because anesthetics transform the solid-gel membrane into a liquid-crystalline state, and because phospholipid membranes display an anomaly in permeability at the phase transition, dimyristoylphosphatidylcholine vesicles were studied at temperatures above the main phase transition to avoid this anomaly.
  • (17) By monitoring the synthesis of specific lens crystallin proteins, and the morphological and cellular changes associated with this differentiated system, we have demonstrated a close correlation between statin expression and cell commitment to the G0 nonreplicative cell cycle state.
  • (18) Developmental regulation of crystallin protein synthesis was observed in rat lenses between embryonic day 19 and postnatal day 21.
  • (19) Bovine lens calf gamma-II crystallin contains five histidine residues at sequence positions 14, 53, 84, 117, and 122.
  • (20) A second crystalline material was observed within cells in the 15,000 X g pellet from spinal fluid.

Semicrystalline


Definition:

  • (a.) Half crystalline; -- said of certain cruptive rocks composed partly of crystalline, partly of amorphous matter.

Example Sentences:

  • (1) Examples are drawn from semicrystalline polymers with flexible chains, liquid-crystalline polymers composed of rigid macromolecules, and amorphous polymers.
  • (2) This paper emphasizes the importance of controlling the crystalline-amorphous microstructure for the antithrombogenicity of polymer surfaces with a semicrystalline microstructure.
  • (3) Images of dense aggregates have a semicrystalline order with the individual polymers adopting simple periodic structures.
  • (4) This complex showed the ordinary transition, except that it yielded a semicrystalline B-form at 66% r.h., suggesting good side-to-side interactions of the material due to some number of cross-bridges of tetramine.
  • (5) Selective area diffraction showed the existence of semicrystalline domains.
  • (6) The swelling limit or equilibrium swelling of semicrystalline or cross-linked polymers and of their gels upon immersion in liquids has been investigated extensively.
  • (7) The following interpretation for the applicability of second-order kinetics to the swelling of semicrystalline polymers, such as gelatin and cellulose, is given.
  • (8) Essential role of crystalline-amorphous microstructured surface in thromboresistant property of semicrystalline segmented copolymer is also discussed in detail.
  • (9) This indicates that lipids next to the receptor protein are not completely immobilized in spite of the semicrystalline organization of the proteins in the postsynaptic region.
  • (10) Since the amount of sorbed-O2 is a function of the chemical nature of the polymer, the type of crystallinity (polymorphism of semicrystalline polymers), the crystalline-amorphous ratio, and so on, a careful study of T1 relaxation as a function of the temperature can define optimal conditions for T1 contrast.
  • (11) Shielding of this peptide bond may therefore be due to protein-protein interactions in the semicrystalline state of the vanadate-bound Ca2+-ATPase in membranous form.
  • (12) Electron-microscopically, semicrystalline inclusions were seen in the mitochondria of the hepatocytes; such inclusions have been reported in several conditions, including erythropoietic protoporphyria and porphyria cutanea tarda, and in control subjects.
  • (13) The experimental results can be interpreted without assuming the major part of water phase in striated muscle to be ice-like or semicrystalline.
  • (14) The semicrystalline nature of the polymer is responsible for the changes in crystallinity.
  • (15) Semicrystalline swollen polymeric networks are prime candidates for biomedical applications.
  • (16) Techniques have also been developed for the preparation of deformable pseudocomposites consisting of layers of swollen semicrystalline and amorphous polymer.
  • (17) A mechanism for failure was presented which assumes that these sutures are bundles of oriented, semicrystalline microfibrils.
  • (18) When long hard segments were present, essentially monophasic, semicrystalline polymers were obtained, with PLA blocks melting around 130 degrees C. Polymers containing longer soft segments (PEO 6000) exhibited a two-phase matrix, with both components being able to crystallize.
  • (19) Since the positronium formation rate in ice is considerably higher than it is in water, there should be a comparable increase in the positronium formation rate in muscle tissue if recent speculation that cellular water is ordered in a semicrystalline icelike state is correct.
  • (20) The currently available theory is found to be in quite good general agreement with a large number of conformational and mixing properties of polymers at interfaces, in semicrystalline polymers, in alkane crystals, in stationary phases used in reversed-phase liquid chromatography, and in amphiphilic aggregates including bilayer membranes and micelles.

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