What's the difference between deoxygenation and hydrogenation?

Deoxygenation


Definition:

  • (n.) The act or operation of depriving of oxygen.

Example Sentences:

  • (1) An example of a most useful and predictive measure of hypoxic stress is optical spectrophotometry which uses time resolved ranging methods to measure optical path lengths to quantitate hemoglobin deoxygenation in tissues.
  • (2) Because the increase in sodium influx was less than that of potassium efflux under slow deoxygenation, SS cells became more dense than those rapidly deoxygenated.
  • (3) Ischemia for 30 min postmortem or in deoxygenated Ringer's solution resulted in marked depletion of adenosine triphosphate (ATP) and creatine phosphate (CP) and an increase in lactate (LAC) of sciatic-tibial nerve of adult male Sprague-Dawley rats.
  • (4) Their erythrocytes displayed sickling upon deoxygenation in vitro.
  • (5) The prominent carbamino resonance at 30.0 ppm upfield of CS(2) is visible in the spectrum of packed, deoxygenated erythrocytes equilibrated in (13)CO(2).
  • (6) The present RS analysis is able to distinguish between oxygenized (OH) and deoxygenized hemoglobin (DOH).
  • (7) More recently, we presented evidence of enhanced transbilayer movement of phosphatidylcholine (PC) in deoxygenated reversibly sickled cells (RSC) and put forward the hypothesis that these abnormalities in phospholipid organization are confined to the characteristic protrusions of these cells.
  • (8) Such observations may conceal the fact that the amine N-oxide has undergone a sequence of deoxygenation and oxygenation reactions only to revert to the parental form and be excreted as such--a process that we propose to call metabolic retroversion.
  • (9) The deoxygenation was homogeneous throughout the solution.
  • (10) This pigment aggregates when deoxygenated to an oligomer with a s20,w equal to 4.7, an aggregation which is reversible upon subsequent oxygenation.
  • (11) The data presented failed to establish relationships between chemical structure and deoxygenative effect of the drugs.
  • (12) The solution binding studies were conducted with deoxygenated hemoglobin and carbonmonoxyhemoglobin with low (50 mM) and high (2 M) salt concentrations.
  • (13) This departure was greatest for salt-free hemoglobin solution, which may be caused by an electrical potential formed by a pH gradient in the layer as oxyhemoglobin is deoxygenated.
  • (14) In addition, in model experiments we studied the effect of deoxygenation of haemoglobin on intensity of the fluorescence and reflected lights measured at 450 nm and 366 nm, respectively.
  • (15) In the absence of 2,3-diphosphoglyceric acid, modification of alpha subunits increases the oxygen affinity and reduces the conformational change of the tetramer upon deoxygenation whereas modification of beta subunits has no effect.
  • (16) 21: 1747, 1975), in which H2O2 is gradually added to a sample of deoxygenated blood that contains an excess of catalase.
  • (17) Since oxyHbS does not aggregate while deoxyHbS does, in a temperature-dependent fashion, the formation of carbamoyldeoxyHbS interferes with such aggregation in vitro in deoxygenated samples.
  • (18) Deoxygenated AS red cells were forced to sickle by lowering the pH, raising the osmolarity of the buffer (sickling pulse).
  • (19) The spectra of the deoxygenated forms, on the other hand, are markedly altered.
  • (20) Deoxygenation of sickle cells is known to increase cation permeabilities (Na+, K+, and Ca2+).

Hydrogenation


Definition:

  • (n.) The act of combining with hydrogen, or the state of being so combined.

Example Sentences:

  • (1) The hypothesis that proteins are critical targets in free radical mediated cytolysis was tested using U937 mononuclear phagocytes as targets and iron together with hydrogen peroxide to generate radicals.
  • (2) It has been conformed that catalase from bovine liver eliminates only the pro R hydrogen atom from ethanol.
  • (3) We investigated the possible contribution made by oropharyngeal microfloral fermentation of ingested carbohydrate to the generation of the early, transient exhaled breath hydrogen rise seen after carbohydrate ingestion.
  • (4) Hydrogen isotope effects on these mutants indicate that MotA catalyzes proton transfer.
  • (5) Excessive accumulation of hydrogen ions in the brain may play a pivotal role in initiating the necrosis seen in infarction and following hyperglycemic augmentation of ischemic brain damage.
  • (6) Studies were conducted in isolated, buffer-perfused rat lungs to determine if prostaglandin (PG) E1 attenuated pulmonary edema provoked by hydrogen peroxide (H2O2).
  • (7) All N and O atoms except N(3) and O(4') participate in a three-dimensional hydrogen-bonding system.
  • (8) Both adiphenine.HCl and proadifen.HCl form more stable complexes, suggesting that hydrogen bonding to the carbonyl oxygen by the hydroxyl-group on the rim of the CD ring could be an important contributor to the complexation.
  • (9) Control mutant S38N has stability essentially the same as that of wild-type lysozyme but hydrogen bonding similar to that of the stabilizing mutant S38D.
  • (10) High intensity ultrasound also enhances the heterogeneous catalysis of alkene hydrogenation by Ni powders.
  • (11) An atmosphere of hydrogen eliminates this inhibition in the hydrogenase-containing T. foetus but not in E. invadens which lacks the enzyme.
  • (12) Vanadate-dependent oxidation of either pyridine nucleotide was inhibited by the addition of either superoxide dismutase or catalase, indicating that both superoxide and hydrogen peroxide may be intermediates in the process.
  • (13) Our findings suggest that (a) the inclusion of a liquid meal provides a reproducible method of measuring orocaecal transit using the lactulose hydrogen breath test, (b) rapid small bowel transit in thyrotoxicosis may be one factor in the diarrhoea which is a feature of the disease and (c) if altered gut transit is the cause of sluggish bowel habit in hypothyroidism, delay in the colon, and not small bowel, is likely to be responsible.
  • (14) Stepwise hydrogenation of metal tetradehydrocorrin salts (10 double bonds) yields a series of macrocycles containing 9, 8, 7, 6 and 5 double bonds and conditions necessary to obtain corrins have been established.
  • (15) For dipeptides containing the amino terminal residues glycine, alanine and phenylalanine, abstraction of the hydrogen from the carbon adjacent to the peptide nitrogen was the major process leading to the spin-adducts.
  • (16) (7) The first-order radical transformation rates are independent of the (initial) concentration of N3 or peptide and unaffected by urea (as a modifier of hydrogen bond structures).
  • (17) Intermolecular contacts occur in both oligomers in the minor groove: in the B form through twisted guanine-guanine hydrogen bonding, and in the Z form through base-base stacking and the water network.
  • (18) Equilibrium-partitioning measurements indicate that the relative affinities of different probes for PC-rich vesicles, in competition with HODMA or DOTAP vesicles, increase with increasing hydrogen-bonding capacity of the probe headgroup in the order PC less than N,N-dimethyl PE less than N-methyl PE less than PE approximately phosphatidyl-2-amino-1-propanol.
  • (19) When tissue metabolism was irreversibly inhibited by exposure to formaldehyde, hydrogen ion concentration and pCO2 were significantly decreased in the mucosal side of the chamber compared with the viable gall bladder.
  • (20) Based on the refined atomic coordinates of the tRNAphe in the orthorhombic crystal, on the recent advances in the distance dependence of the ring-current magnetic field effects and on the adopted values for the isolated hydrogen-bonded NH resonances, a computed spectrum consisting of 23 protons was constructed.

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