(1) Inhibition was prevented by competitive inhibitors or substrates, indicating that the action of ferrate was site-specific.
(2) The results allow to expect that a reactive histidine is present in enzyme's active site and that this aminoacid is modified with ferrate.
(3) It was also shown that the enzyme was inactivated with ferrate ion, structural analogue of orthophosphate and strong oxidizing agent.
(4) Amino acid analysis indicated that methionine 512 is the target site in this peptide for ferrate oxidation.
(5) Potassium ferrate is a very strong oxidant and is highly soluble in water.
(6) Nitrosamines, which are potent carcinogens, are widespread throughout the environment and can be eliminated from waste water effluent by the action of potassium ferrate.
(7) Treatment of murine leukemia virus reverse transcriptase (MuLV RT) with potassium ferrate, an oxidizing agent known to oxidize amino acids involved in phosphate binding domains of proteins, results in the irreversible inactivation of both the DNA polymerase and the RNase H activities.
(8) Ferrate inactivation at pH 5.0 is accompanied by the modification of only one amino acid.
(9) Two compounds, a zeolite, clinoptilolite, and a ferrocyanide, potassium hexacyanocobalt (II) ferrate (II), were found to be the most effective adsorbers of caesium in vitro.
(10) Activation is shown to be strictly a redox process and can be rapidly accomplished by using ferricyanide, cobalt terpyridine or tetracyanomonophenanthroline ferrate, and a control electrode to control solution potential.
(11) Potassium ferrate (K2FeO4) is useful in the advanced treatment of waste water.
(12) Methionine was measured on the basis of color reaction with sodium pentacyano-nitrosyl-ferrate in alkaline solution.
(13) It makes me think of Arnold Bennett, whose novels financed the purchasing of yachts, or Somerset Maugham, who retired to a villa in Cap Ferrat.
(14) Analogous electron-transfer reactions between soluble iron and bis(dipicolinato)cobaltate(III) or bis(dipicolinato)ferrate(II) were studied by stopped-flow spectrophotometry under solution conditions identical with those of the rusticyanin experiments.
(15) Amino acid sequence analysis of peptides I and II suggested Lys-285 and Cys-635 as the probable sites of ferrate action.
(16) Among complexes studied here, the bis(o-xylyldithiolato) ferrate(III) monoanion gave the MCD spectrum which resembles that of a rubredoxin.
(17) Potassium ferrate, an analog of orthophosphate and a potent oxidizing agent, was found to irreversibly inactivate porcine muscle adenylate kinase.
(18) Also extracted from the membranes is the ferrated form of MAIC, FeMAIC.
(19) In addition, comparative high pressure liquid chromatography tryptic peptide maps obtained before and after ferrate oxidation demonstrated that only five peptides of the more than 60 peptide peaks present in the tryptic digest underwent a major change in either peak position or intensity as a result of ferrate treatment.
(20) Potassium ferrate and the nitrosamine was placed in aqueous solution and allowed to react to completion.
Iron
Definition:
(n.) The most common and most useful metallic element, being of almost universal occurrence, usually in the form of an oxide (as hematite, magnetite, etc.), or a hydrous oxide (as limonite, turgite, etc.). It is reduced on an enormous scale in three principal forms; viz., cast iron, steel, and wrought iron. Iron usually appears dark brown, from oxidation or impurity, but when pure, or on a fresh surface, is a gray or white metal. It is easily oxidized (rusted) by moisture, and is attacked by many corrosive agents. Symbol Fe (Latin Ferrum). Atomic weight 55.9. Specific gravity, pure iron, 7.86; cast iron, 7.1. In magnetic properties, it is superior to all other substances.
(n.) An instrument or utensil made of iron; -- chiefly in composition; as, a flatiron, a smoothing iron, etc.
(n.) Fetters; chains; handcuffs; manacles.
(n.) Strength; power; firmness; inflexibility; as, to rule with a rod of iron.
(n.) Of, or made of iron; consisting of iron; as, an iron bar, dust.
(n.) Resembling iron in color; as, iron blackness.
(n.) Like iron in hardness, strength, impenetrability, power of endurance, insensibility, etc.;
(n.) Rude; hard; harsh; severe.
(n.) Firm; robust; enduring; as, an iron constitution.
(n.) Inflexible; unrelenting; as, an iron will.
(n.) Not to be broken; holding or binding fast; tenacious.
(v. t.) To smooth with an instrument of iron; especially, to smooth, as cloth, with a heated flatiron; -- sometimes used with out.
(v. t.) To shackle with irons; to fetter or handcuff.
(v. t.) To furnish or arm with iron; as, to iron a wagon.
Example Sentences:
(1) The hypothesis that proteins are critical targets in free radical mediated cytolysis was tested using U937 mononuclear phagocytes as targets and iron together with hydrogen peroxide to generate radicals.
(2) The most successful dyes were phenocyanin TC, gallein, fluorone black, alizarin cyanin BB and alizarin blue S. Celestin blue B with an iron mordant is quite successful if properly handled to prevent gelling of solutions.
(3) These membrane perturbation effects not observed with bleomycin-iron in the presence of a hydroxyl radical scavenger, dimethyl thiourea, or a chelating agent, desferrioxamine, were correlated with the ability of the complex to generate highly reactive oxygen species.
(4) The specific activities of extracts from cells grown under phototrophic and aerobic conditions were similar and not affected by the concentration of iron in the growth media.
(5) In the 153 women to whom iron supplements were given during pregnancy, the initial fall in haemoglobin concentration was less, was arrested by 28 weeks gestation and then rose to a level equivalent to the booking level.
(6) Typically the iron-iron axis (gz) of the binuclear iron-sulfur clusters is in the membrane plane.
(7) Increased iron levels in basal ganglia were generally associated with normal or elevated levels of ferritin immunoreactivity, for example, the substantia nigra in PSP and possibly MSA, and in putamen in MSA.
(8) Lead levels in contents and shells of eggs laid by hens dosed with all-lead shot were about twice those in eggs laid by hens dosed with lead-iron shot.
(9) Dietary factors affect intestinal P450s markedly--iron restriction rapidly decreased intestinal P450 to beneath detectable values; selenium deficiency acted similarly but was less effective; Brussels sprouts increased intestinal AHH activity 9.8-fold, ECOD activity 3.2-fold, and P450 1.9-fold; fried meat and dietary fat significantly increased intestinal EROD activity; a vitamin A-deficient diet increased, and a vitamin A-rich diet decreased intestinal P450 activities; and excess cholesterol in the diet increased intestinal P450 activity.
(10) Since iron from fortified formulas is well absorbed during the first three months of life, even if it is not immediately used for hemoglobin formation, an inccrease in the iron stores will occur...
(11) Dietary intakes, measured by three 24-hour recalls, revealed that protein, iron and Vitamin C generally met or exceeded the Nutrition Recommendations for age.
(12) This is a struggle for the survival of our nation.” As ever, after Trump’s media dressing-down, his operation was quick to fit a velvet glove to an iron fist.
(13) Ten weeks of iron therapy was not, however, long enough to increase iron stores.
(14) With both approaches, carbohydrate and fat had little influence whereas egg albumin had a significant inhibitory effect on the absorption of nonheme iron.
(15) The protein quality and iron bioavailability of mechanically deboned turkey meat (MDT) and hand-deboned turkey meat (HDT) were determined in rats.
(16) Serum levels of vitamins A and E, zinc and iron were determined in healthy control subjects and lepromatous leprosy patients belonging to an eastern state of India.
(17) Ferric iron in aqueous solution was used as an iron-only control.
(18) The implications of inhibition of protein kinase C by adriamycin-iron(III) are discussed.
(19) The duodenal mucosa of genotypically normal iron replete and iron deficient mice and mice with sex-linked (sla) and microcytic anemias (mk) was examined for the presence of iron-binding proteins.
(20) Ferredoxin reductase (Fd-reductase) supplies reducing equivalents obtained from NADPH to mitochondrial cytochrome P450 enzymes via the small iron-sulfur protein ferredoxin.