What's the difference between metal and organometallic?

Metal


Definition:

  • (n.) An elementary substance, as sodium, calcium, or copper, whose oxide or hydroxide has basic rather than acid properties, as contrasted with the nonmetals, or metalloids. No sharp line can be drawn between the metals and nonmetals, and certain elements partake of both acid and basic qualities, as chromium, manganese, bismuth, etc.
  • (n.) Ore from which a metal is derived; -- so called by miners.
  • (n.) A mine from which ores are taken.
  • (n.) The substance of which anything is made; material; hence, constitutional disposition; character; temper.
  • (n.) Courage; spirit; mettle. See Mettle.
  • (n.) The broken stone used in macadamizing roads and ballasting railroads.
  • (n.) The effective power or caliber of guns carried by a vessel of war.
  • (n.) Glass in a state of fusion.
  • (n.) The rails of a railroad.
  • (v. t.) To cover with metal; as, to metal a ship's bottom; to metal a road.

Example Sentences:

  • (1) In this study of ten consecutive patients sustaining molten metal injuries to the lower extremity who were treated with excision and grafting, treatment with compression Unna paste boot was compared with that with conventional dressing.
  • (2) The LD50 of the following metal-binding chelating drugs, EDTA, diethylenetriaminepentaacetic acid (DTPA), hydroxyethylenediaminetriacetic acid (HEDTA), cyclohexanediaminotetraacetic acid (CDTA) and triethylenetetraminehexaacetic acid (TTHA) was evaluated in terms of mortality in rats after intraperitoneal administration and was found to be in the order: CDTA greater than EDTA greater than DTPA greater than TTHA greater than HEDTA.
  • (3) Our recurrences are due to local infections, removing the metal strut too early, i.e.
  • (4) "Acoustic" craters were produced by two laser pulses delivered into a saline-filled metal fiber cap, which was placed in a mechanically drilled crater.
  • (5) These results indicate that the inhibition of CarAc by heavy metals occurs by binding of the sulfhydryl on the enzyme by the metals.
  • (6) The consequences of proved hypersensitivity in patients with metal-to-plastic prostheses, either present prior to insertion of the prosthesis or evoked by the implant material, are not known.
  • (7) In general, enzyme activity was strongly reduced by heavy metal inorganic cations; less strongly by organometallic cations, some anions, and certain pesticides; and weakly inhibited by light metal cations and organometallic and organic compounds.
  • (8) EGTA was ineffective in removing calmodulin from particulate preparations, but treatment with the tervalent metal ion La3+ resulted in a loss of up to 98% of calmodulin activity from these preparations.
  • (9) Sift the cocoa powder over the top and lightly but thoroughly fold it in with the metal spoon.
  • (10) The results also suggest that both alkali metals most probably have been delivered to the suckling pups and some of their toxic effect was retarded.
  • (11) The radioprotective action in E. coli ATCC 9637 of ascorbate added to media containing the weak sensitizer, tetracycline (effect described by Pittillo and Lucas (1967)), was found to be dependent on the presence of metal catalysts of the autoxidation of ascorbate.
  • (12) This study introduces a simple in vitro arrangement to measure current densities of implant metals.
  • (13) A rubber cuff was fixed on the metal cylinder and let an opening of 8 cm, simulating the cervix uteri.
  • (14) Since the enzyme requires a metal ion (Co2+) we suggest that the RNA and heparin are inhibitory by virtue of their capacity to chelate the Co2+.
  • (15) Lesions of allergic contact type could not be induced in the oral mucosa to any of the metal salt preparations.
  • (16) As yet the observations demonstrate that workers exposed in their occupation to heavy metals (cadmium, lead, metalic mercury) and organic solvents should be subjected to special control for detection of renal changes.
  • (17) This study investigates the photoneutron field found in medical accelerator rooms with primary barriers constructed of metal slabs plus concrete.
  • (18) While a clearcut relationship cannot be established between heavy metal music and destructive behavior, evidence shows that such music promotes and supports patterns of drug abuse, promiscuous sexual activity, and violence.
  • (19) The physiologically important metal ion for catalysis is Mg2+; however, Mn2+ supports in vitro activity, though at a reduced level.
  • (20) We support the view that catalysis by metalloenzymes may be a reflection of the chemistry of the metal ion itself as a Lewis acid, and that perhaps too much emphasis has been placed on supposed special characteristics (such as strains, "entasis") of the enzyme-metal ion association.

Organometallic


Definition:

  • (a.) Metalorganic.

Example Sentences:

  • (1) In general, enzyme activity was strongly reduced by heavy metal inorganic cations; less strongly by organometallic cations, some anions, and certain pesticides; and weakly inhibited by light metal cations and organometallic and organic compounds.
  • (2) A knowledge gained of the biosynthesis of steroids and its specific enzymes helped to initiate my general polyketide theory of biosynthesis and also my idea of outdoing enzyme achievements with organometallic complexes ("inorganic enzyme chemistry").
  • (3) In mice bearing Ehrlich ascites tumor cells, all four compounds inhibited the tumor growth, the organometallic phosphorodithioates being more active than phosphinodithioate analogues, and the organoantimony derivatives more active than organotins.
  • (4) The organometallic compound, trimethyltin (TMT), is used as a selective denervation tool to validate morphological, biochemical and functional approaches to the detection and characterization of neurotoxicity.
  • (5) Studies on structure-activity relationships of organometallic anticancer drugs are reviewed.
  • (6) An immunoassay method based on the labelling of an antigen with a transition-metal carbonyl organometallic marker and detection of the label by Fourier transform infrared (FT-IR) spectroscopy is described.
  • (7) Supercritical fluid chromatography coupled with inductively coupled plasma mass spectrometry shows high potential for the determination at ultratrace levels of organometallic compounds of environmental interest.
  • (8) Corrinoids are central cofactors in bacterial metabolism, where they participate in a series of organometallic and redoxprocesses.
  • (9) This pathway is unique in that the major intermediates are enzyme-bound and are often organometallic complexes.
  • (10) The only active nongold organometallic complex was spirogermanium which had an equivalent IC50 for activity as AF.
  • (11) Resonance Raman spectra are reported for the organometallic phenyl-FeIII complexes of horse heart myoglobin.
  • (12) Non-platinum-group metal antitumor agents are represented by inorganic and organometallic compounds which contain either main-group metals such as gallium, germanium, and tin, or transition metals such as titanium, vanadium, iron, copper, and gold.
  • (13) This arrangement permits the metal to take part in the kinds of organometallic reactions that are ideal for coenzyme B-12 catalysis, including oxidative addition and its reverse, reductive elimination.
  • (14) Three new organometallic compounds, with iminodiacetic acid as the 99mTc chelating group and 2,3-diaminopropionamide as the platinum complexing group, have been prepared and characterized.
  • (15) Toxic elements that form organometallic compounds, especially the metal-alkyls (e.g., methylmercury), deserve special concern.
  • (16) On the other hand, the alpha-face of the A-ring of estradiol did tolerate positively charged organometallic fragments bearing bulky substituents although the RBA value tended to decrease with increasing charge.
  • (17) The validity of the technique has been tested in a phenobarbital assay using as the marker a cyclopentadienylmanganese (I) tricarbonyl (cymantrene) moiety, ethyl acetate extraction to separate the free and bound organometallic fractions, and FT-IR spectroscopy to detect the CO stretching modes of the organometallic label.
  • (18) The data indicate that protein-energy deficiency may impair the absorption of zinc by the rat intestinal mucosa in the presence of low-molecular-weight substances of high affinity for zinc, without altering the absorption of amino acids, or of zinc organometallic complexes in which the metal is tightly bound.
  • (19) The majority of this material was present as an organometallic form of manganese other than CMT.
  • (20) The water-soluble organometallic complex cis-[Pt(Me)2(Me2SO)2] (Me = methyl; Me2SO = dimethyl sulfoxide) (cis-dimethyl platinum(II); CDMP) was evaluated for its toxicity on the rat and for its efficacy against two tumors of this animal: the Yoshida ascites sarcoma and the T8 sarcoma of GuĂ©rin.

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