What's the difference between metamerism and tautomerism?

Metamerism


Definition:

  • (n.) The symmetry of a metameric structure; serial symmetry; the state of being made up of metameres.
  • (n.) The state or quality of being metameric; also, the relation or condition of metameric compounds.

Example Sentences:

  • (1) This is especially evident on the ventral surface of the metamerically arranged axial muscles.
  • (2) The sloppy paired locus is involved in the establishment of the metameric body plan of the Drosophila embryo.
  • (3) In Haemopis embryos labeling of both nerve fibers and cell bodies with the antibody appears as expected for a metameric animal in a rostrocaudal temporal gradient from about day 5-6.
  • (4) These six metameres also are responsible for the existence of the pronephros.
  • (5) In each metamere, the area of cell migration takes place near the caudal border of the somite and, from one somite to the other, the number of migrating cells increases in a cephalo-caudal direction.
  • (6) The differences in levels between males and females and between anatomical regions during imaginal life suggest, in this species of cockroach, the physiological importance of the metameric organization in metabolic pathways or functional aspects of biogenic amines.
  • (7) Prior to dorsal closure, expression of the Drosophila gene is observed in non-neuronal tissues, especially in the mesectoderm and presumptive epidermis, both in a metameric pattern.
  • (8) Moreover, such a causative role of cell lineage is suggested by cases where homologous cell types characteristic of a symmetrical and longitudinally metameric body plan arise via homologous cell lineages.
  • (9) The case is characterized by successful counteracting the main clinical manifestations of Raynaud's phenomenon by the local metameric application of cerebrolysin (neuromeric, scleromeric puncturing) employed by the authors for the first time for the disease treatment.
  • (10) In mild contusion of the first-second segments the leading clinical symptoms in the acute period were pareses of the arms and paralyses of hands with retained reflexes and insignificant impairments of sensitivity in fingers, i.e., the level of clinical manifestations did not correspond with the conventional segmento-metameric innervation.
  • (11) A second group of patients had SAs that remained unchanged despite AVM changes (six of seven of these were in patients with metameric angiomatosis).
  • (12) The larval development of P. porosa is characterized by its passing in the cavity of the external cyst, by the complete separation of anlages of the body of the larva and cercomere at the metamere stage and by the intensive growth of the cercomere after the invagination of the larva.
  • (13) Life forms of plants are divided into thirteen types corresponding to the nature of their basic metameres.
  • (14) The invagination process of the metamere is described.
  • (15) This metameric migration pattern is thought to be caused by molecular differences between the rostral and caudal portions of the somite.
  • (16) Identification of specific neuronal populations and their projections in the developing hindbrain reveals a segmental organization in which pairs of metameric epithelial units cooperate to generate the repeating sequence of cranial branchiomotor nerves.
  • (17) In all three organisms, the pattern of engrailed expression at the segmented germ band stage is similar, and the parasegments are the first metameres to form.
  • (18) When neural crest cells were ablated surgically prior to their emigration from the neural tube, the pattern of T-cadherin immunoreactivity was unchanged compared to unoperated embryos, suggesting that the metameric T-cadherin distribution occurs independent of neural crest cell signals.
  • (19) Each nerve is in relation with a column of motoneurons whose both the metameric extension and the exact topography in the anterior horn have been defined.
  • (20) It allows to accurately reach the desired metameric level, avoiding massive sympathetic blockade, and providing a steady hemodynamic condition.

Tautomerism


Definition:

  • (n.) The condition, quality, or relation of metameric substances, or their respective derivatives, which are more or less interchangeable, according as one form or the other is the more stable. It is a special case of metamerism; thus, the lactam and the lactim compounds exhibit tautomerism.

Example Sentences:

  • (1) The coupled dienone-phenol re-arrangement and keto-enol tautomerism of this quinone methide produce the observed 3,4-dihydroxybenzaldehyde.
  • (2) On the other hand, results indicate that the protonation of formycin and its derivatives at the N1 atom leads to a change in their tautomeric preference from N7-H to N8-H.
  • (3) The inhibitor trapping system, however, prevents the inactivation of succinate dehydrogenase under the conditions when the rate of tautomeric oxaloacetate enol in equilibrium oxaloacetate ketone interconversion is high.
  • (4) In contrast, equilibria of ring chain tautomerism and covalent hydration of aldoses are almost completely insensitive to the polarity of their surroundings.
  • (5) The importance of both tautomerism and protonation reactions in the mechanism of action of adenosine deaminase is studied by means of a quantitative structure activity relationships strategy.
  • (6) The possibility that this product is an equilibrium mixture with the tautomeric 4-hydroxycyclophosphamide has not been as yet defintely ruled out.
  • (7) In addition to being a possible mechanism for alteration of hydrogen bonding in oxidized DNA, this type of interaction gives a better understanding into N7-N9 tautomerism of adenine.
  • (8) The product 3-fluorooxalacetate is thus released from phosphoenolpyruvate carboxykinase as the keto form and is reduced more rapidly by reduced nicotinamide adenine dinucleotide with malate dehydrogenase than by the occurrence of tautomerization.
  • (9) These results strongly suggest that the anomeric, epimeric, and tautomeric form of the sugar phosphate substrates favored by both enzymes is the beta-D-fructofuranose form.
  • (10) Tautomerization of DOPA quinone to dehydroDOPA may thus be a factor in the sclerotization of natural structures incorporating DOPA containing proteins.
  • (11) For the complex formed between [5,5-2H,5-13C]ALA and methyl methanethiosulfonate (MMTS) modified PBG synthase, which does not catalyze PBG formation but can form a Schiff base adduct, the chemical shift of 44.2 ppm (line width 92 Hz) identifies an imine structure as the predominant tautomeric form of the Schiff base.
  • (12) delta 5-3-Ketosteroid isomerase (EC 5.3.3.1) catalyzes the isomerization of delta 5-3-ketosteroids to delta 4-3-ketosteroids by a conservative tautomeric transfer of the 4 beta-proton to the 6 beta-position with Tyr-14 as a general acid and Asp-38 as a general base [Kuliopulos, A., Mildvan, A. S., Shortle, D., & Talalay, P. (1989) Biochemistry 28, 149-159].
  • (13) The results are consistent with evidence for the formation of the first tetrahydropterin intermediate by a tautomerization without any requirement for NADPH.
  • (14) Its function is probably to maintain the orientation and tautomeric state of the imidazole ring of histidine-159.
  • (15) This suggests that a stable AP:C base mispair via two hydrogen bonds can be formed with the imino tautomer of C. These results stress the importance of the imino form of C in AP-induced mutagenesis and support the 'trigger mechanism', in which formation of one hydrogen bond between AP and C is considered to stimulate the tautomeric shift of AP or C. The calculated relative stabilities of various base pairs and mispairs were in good agreement with experimental findings.
  • (16) Whereas O6-MeGua did not form hydrogen bonds with cytosine (via usual, wobble, or unusual tautomeric structures), it did form a 1:1 hydrogen-bonded complex with protonated cytosine.
  • (17) Amide-imide tautomerism enables a cleanup of the extract.
  • (18) Ultraviolet and infrared spectrophotometric techniques have been utilized to demonstrate that the monoanionic form of 2-thiouracil in aqueous medium consists of an equilibrium mixture of two tautomeric monoanions, one due to dissociation of the N1 proton, the other to dissociation of the N3 proton, in the approximate ratio 1:1.
  • (19) Combined use of mass spectroscopy and 1H- and 13C-NMR spectroscopy established that it is the 4,8-anhydro derivative of N-acetylneuraminic acid and that in solutions it exists in two tautomeric forms.
  • (20) As a result of a concerted proton (tautomeric) shift in the linked residues of the hydrogen-bond chain, which includes the bound molecule, a charge separation occurs.