What's the difference between sulphur and thiol?

Sulphur


Definition:

  • (n.) A nonmetallic element occurring naturally in large quantities, either combined as in the sulphides (as pyrites) and sulphates (as gypsum), or native in volcanic regions, in vast beds mixed with gypsum and various earthy materials, from which it is melted out. Symbol S. Atomic weight 32. The specific gravity of ordinary octohedral sulphur is 2.05; of prismatic sulphur, 1.96.
  • (n.) Any one of numerous species of yellow or orange butterflies of the subfamily Pierinae; as, the clouded sulphur (Eurymus, / Colias, philodice), which is the common yellow butterfly of the Eastern United States.

Example Sentences:

  • (1) That suggests they are being replenished by sulphur dioxide, most probably from volcanoes.
  • (2) Sulphuric acid fluorescence is used for quantitation and specificity is achieved by the addition of tritiated oestrone to the urine hydrolysate.
  • (3) Liver scintigraphy with 67-Ga citrate and alphafetoprotein (afp) determinations in the serum were carried out in 84 patients with liver mass lesions in the preceding sulphur colloid scans.
  • (4) The use of sulphur-containing amino acids and 2-deoxyglucose in growth media led to impaired cell wall synthesis and rendered cells very susceptible to treatment with mercapto-ethanol and various lytic enzymes.
  • (5) The molecular mass (5988 Da) of the native rubredoxin has been measured by electrospray-ionization m.s., thus establishing the applicability of the technique to this type of iron-sulphur protein.
  • (6) Attention is drawn to the shortcomings in our current knowledge of the scale of turnover of the sulphur cycle and of our understanding of the microorganisms involved in specialized environments.
  • (7) N-Methylformamide extracts of acid-treated precipitated VFe protein of the V-nitrogenase of Azotobacter chroococcum are yellow-brown in colour and contain vanadium, iron and acid-labile sulphur in the approximate proportions 1:6:5.
  • (8) Here we show that a farnesyl moiety is attached to a sulphur atom of the C-terminal cysteine of T gamma-2 (active form), a part of which is additionally methyl-esterified at the alpha-carboxyl group.
  • (9) Erabutoxin a was partially hydrolysed with enzymes and sulphuric acid and the resulting peptides were separated from each other by column chromatography and paper electrophoresis.
  • (10) NADH:ubiquinone reductase, the respiratory chain complex I of mitochondria, consists of some 25 nuclear-encoded and seven mitochondrially encoded subunits, and contains as redox groups one FMN, probably one internal ubiquinone and at least four iron-sulphur clusters.
  • (11) Bacteria of the genus Thiobacillus can obtain energy from the chemolithotrophic oxidation of inorganic sulphur and its compounds (sulphide, thiosulphate and polythionates) and use this energy to support autotrophic growth on carbon dioxide.
  • (12) Bacteriophage mu2 is inactivated by both mono- and di-functional sulphur mustards at relatively low extents of alkylation.
  • (13) The study of amino acid pattern shows that sulphur containing amino acids are limiting to almost the same degree in meat and meat soy blend.
  • (14) In a case in which ovarian biopsy at laparotomy revealed typical actinomycotic "sulphur granules" and Actinomyces israelii was diagnosed, standard Actinomyces israelii cytoplasmic antigens and circulating C1-binding immune complexes were found in the patient's serum when it was tested by counterimmunoelectrophoresis.
  • (15) Experiments were performed in a cylinder full of beads open at one end and closed at the other in which a mixture of oxygen with helium or argon or sulphur hexafluoride could diffuse with ambient air through the open end.
  • (16) The results obtained indicated that both the sulphydration and trans-sulphuration pathways were operating.
  • (17) This effect may add to other factors decreasing sulphur availability in critically ill patients, and simultaneous administration of thiosulphate is therefore recommended to ensure a safe SNP treatment during and after coronary bypass operations.
  • (18) (4) There is no specific therapy for poisoning by sulphur mustard.
  • (19) Among various acetylated proteins, proteins insoluble in 0.1m-sulphuric acid have the highest radioactivity.
  • (20) Desulfovibrio africanus ferredoxin III is a monomeric protein (Mr 6585) containing seven cysteine residues and 7-8 iron atoms and 6-8 atoms of acid-labile sulphur.

Thiol


Definition:

Example Sentences:

  • (1) Conversion of the active-site thiol to thiocyanate makes it more difficult to inactivate the enzyme by treatment with Cd2+.
  • (2) Loss of reduced protein thiols, as measured by binding of the thiol reagent iodoacetic acid to GPD, and loss of GPD enzymatic activity occurred in a dose-dependent manner.
  • (3) The synthetic S-nitroso-thiol, S-nitroso-N-acetylcysteine, markedly inhibited platelet aggregation with an IC50 of 6 nM.
  • (4) Based on incorporation of radioactively labeled N-ethylmaleimide, the readily reactive thiol groups of isolated myosin (EC 3.6.1.3) from fast, slow and cardiac muscles could be classified into 3 types.
  • (5) The enzyme was inhibited by thiol and carbonyl reagents.
  • (6) The thiol-conjugating capacity of quinones may, however, be applied to reduce the tissue-damaging effects of stimulated neutrophils.
  • (7) In vitro inhibition of the heme-containing enzyme delta-aminolevulinic acid dehydratase by ATG was reversible in the presence of physiological concentrations of small thiols.
  • (8) The reactivity of the three disulphide bridges of insulin towards sodium sulphite was studied by amperometric titration of the liberated thiol groups.
  • (9) Heterogeneity in thiol content of sperm within individual samples was also observed.
  • (10) Both benzyl alcohol dehydrogenase and benzaldehyde dehydrogenase II were inhibited by the thiol-blocking reagents iodoacetate, iodoacetamide, 4-chloromercuribenzoate and N-ethylmaleimide.
  • (11) In the normal lens, we found nearly 10% of the total nonprotein thiols bound to the protein.
  • (12) The choice of 400 nm to monitor the reaction excludes the interference of other intermediates in the reaction of ebselen with thiols as well as the reaction of the thiols with CDNB.
  • (13) The sulfhydryl enzyme malate synthase was inactivated by X-irradiation in air-saturated aqueous solution, in the absence or presence of a variety of additives (thiols, antioxienzymes, typical radical scavengers, inorganic salts, buffer components, substrates, products, analogues).
  • (14) Based on the iodoacetamide inactivation and disulfide protection of thioltransferase activity, a model for the catalytic mechanism of the thiol-disulfide oxidoreduction is proposed.
  • (15) These results suggested that in isolated adipocytes: there are high-affinity and low-affinity receptors, but the low-affinity receptors are absent at 21 degrees C; the binding of oxytocin can be regulated by insulin, and growth factors; and the oxytocin receptors contain disulfide bridges and free thiols that are essential for the maintenance of oxytocin binding.
  • (16) Finally, there has been considerable interest in supplying thiols by use of the SH-containing angiotensin converting enzyme inhibitors, such as captopril.
  • (17) The thiol oxidizing agent diamide inhibited both vaso- and bronchoconstriction induced by H2O2, AA, or U-44069.
  • (18) IPNS was rapidly inhibited by the thiol-blocking reagents N-ethylmaleimide and 2,2'- and 4,4'-dipyridyl disulphide, but not by 5,5'-dithiobis-(2-nitrobenzoic acid) in the same concentration.
  • (19) Interaction of Se with SeBP is completely blocked by thiol inhibitors.
  • (20) Effects on CLE formation, morphology, PA, and ornithine decarboxylase activities, EGF binding, and thiol levels were evaluated using 40% growth inhibitory concentrations.