What's the difference between ether and etherification?

Ether


Definition:

  • (n.) A medium of great elasticity and extreme tenuity, supposed to pervade all space, the interior of solid bodies not excepted, and to be the medium of transmission of light and heat; hence often called luminiferous ether.
  • (n.) Supposed matter above the air; the air itself.
  • (n.) A light, volatile, mobile, inflammable liquid, (C2H5)2O, of a characteristic aromatic odor, obtained by the distillation of alcohol with sulphuric acid, and hence called also sulphuric ether. It is powerful solvent of fats, resins, and pyroxylin, but finds its chief use as an anaesthetic. Called also ethyl oxide.
  • (n.) Any similar oxide of hydrocarbon radicals; as, amyl ether; valeric ether.

Example Sentences:

  • (1) It was shown in experiments on four dogs by the conditioned method that the period of recovery of conditioned activity after one hour ether anaesthesia tested 7 to 7.5 days.
  • (2) After 3 and 6 months, blood collected by cardiocentesis using ether anesthesia and then sacrificed to remove CNS and internal organs.
  • (3) Glycosyl ceramide concentration was determined by gas-liquid chromatography of the trimethylsilyl ethers of the methyl glycosides.
  • (4) Ether extracts were analyzed by gas chromatography-mass spectrometry (GC-MS) and various chlorinated and non-chlorinated compounds were detected, e.g.
  • (5) 1 Rats were convulsed once daily for 7 days by exposure to the inhalant convulsant agent, flurothyl (Indoklon, bis (2,2,2-trifluouroethyl)ether).
  • (6) No impurities in the technical grade ether influenced the responses.
  • (7) Depletion of extracellular Ca2+ by EGTA [ethylene glycol-bis(beta-aminoethyl ether)-N,N,N'N'-tetraacetic acid] attenuated both [Ca2+]i increase and superoxide production induced by particles.
  • (8) It was presumed that thymohydroquinone is excreted as ethereal sulfuric acid conjugate in man.
  • (9) The authors have carried out an experimental study of an insufficiently explored problem of the diffusion capacity of the ethers of cholesterol through the skin and the possibility of their intra-articular transport with cholesterol ether of the oleic acid marked 1,2(3)H taken as an example.
  • (10) Chelation of extracellular calcium with ethyleneglycol-bis(beta-aminoethyl ether)N,N,N',N' tetraacetic acid (EGTA) did not abolish the increase in calcium.
  • (11) The UE and KE fractions were then separated by silicic acid column chromatography with a stepwise elution method using ether-hexane.
  • (12) The enzyme appears to be highly specific since D-dopachrome, alpha-methyldopachrome, dopaminochrome, adrenochrome methyl ether and deoxyadrenochrome are not substrates.
  • (13) After introduction of surgical anesthesia with general agents such as ether and chloroform, a large number of deaths due to anesthetic toxicity were reported.
  • (14) Data of ether-extracted total fat content versus data of fat marbling planimetry correlated well with r = 0.9.
  • (15) When the enzyme is inactivated with 16alpha-[2-3H]bromoacetoxyestradiol 3-methyl ether, amino acid analysis of acid hydrolysates reveals 3-carboxymethylhistidine and 1,3-dicarboxymethylhistidine.
  • (16) In addition these methods of estrogen treatment potentiated the ether-induced increase in plasma prolactin in the morning (9.00-11.00) beginning on week 2 and continuing for 3-8 weeks.
  • (17) Studies of structure-transacylation relationships for a series of acylhydroxamic acids of chlorinated biphenyl ethers and their related compounds by rat liver N-arylacylhydroxamic acid-dependent N-acyltransferase (AHNAT) are described.
  • (18) The biologically inactive phorbol ester 12-O-tetradecanoyl phorbol-13-acetate methyl ether (10 nM) had no effect on 45Ca2+ uptake.
  • (19) Steroids were extracted with ethyl ether, and cortisol was purified by gel column chromatography prior to assay.
  • (20) The method comprised adsorption on Extrelut column from alkaline plasma, elution with diethyl ether-methylene chloride, evaporation in the presence of 0.01 M hydrochloric acid and injection of the acid solution onto a mu Bondapak C18 column, using acetonitrile-0.025 M potassium dihydrogenphosphate as mobile phase and ultraviolet detection at 210 nm.

Etherification


Definition:

  • (n.) The act or process of making ether; specifically, the process by which a large quantity of alcohol is transformed into ether by the agency of a small amount of sulphuric, or ethyl sulphuric, acid.

Example Sentences:

  • (1) Thus, as it proceeds, this etherification leads to products having higher reactivity towards the epoxide.
  • (2) The feature distinguishing the effect produced by the ration with saccharose, as compared with that containing starch, was an accelerated etherification of cholesterol in the blood.
  • (3) This suggests that de-etherification could occur, leading to estradiol.
  • (4) The etherification of the alcohol functions of oestradiol allows an adequate protection of the hormone against hepatic catabolism.
  • (5) The study described the technique for gas chromatographic identification of sebacic acid in the work zone air in the form of diethyl ether produced due to sebacic acid etherification by absolute ethyl alcohol in the presence of 0.3 ml of concentrated sulphuric acid during heating up to 70 degrees C for 15 min.
  • (6) Evaluation of these derivatives against murine P-388 lymphocytic leukemia indicated that, while the hydroxyphenyl styryl ketones and related esters were devoid of significant anticancer activities, etherification of the nuclear hydroxyl group gave compounds with a discernible increase in mean survival time.
  • (7) The results of quantitative acetic acid determination in the cadaveric organs by LGC method after etherification are influenced upon by its "background" values.
  • (8) Considerable differences in the reactivities toward acylation and etherification of the two axial hydroxyl groups in 4 permitted the preparation, in good yields, of the 4-acetate (9) and of the 4-methyl ether (12).
  • (9) Etherification of the phenolic group of 7 by N-(2-chloroethyl)pyrrolidine and subsequent methanesulfonate salt formation provided [3,4-dihydro-2-(4-methoxyphenyl)-1-maphthalenyl]]4-]2-(1-pyrrolidinyl)ethoxy]phenyl]methanone, methane sulfonic acid salt (3).
  • (10) Arteether (6) has been prepared from dihydroquinghaosu (3) by etherification with ethanol in the presence of Lewis acid and separated from its chromatographically slower moving alpha-dihydroqinghaosu ethyl ether (7).
  • (11) The vindoline radical thus formed eliminates a second electron and a proton to produce a highly reactive iminium derivative which undergoes intramolecular etherification and dimerization.
  • (12) On the basis of the estimate of the raw material use for regeneration of butyl acetate from the butanol-butyl acetate solutions by etherification of butanol with acetic anhydride, the technical and economic advantages of the processing of such solutions by the described method were shown.
  • (13) Substitution of the glycosidic moiety of 1 or 2 by ester and ethers, as well as the esterification and etherification of alpha-peltatin (4) including its glucosidic ethylidene and thenylidene cyclic acetals (25 and 26), has afforded compounds of much less activity than that of 1.
  • (14) Blockage of the C-9 carbinolamide via etherification markedly reduces antileukemic and cytotoxic activity and slightly reduces antitubulin activity but has relatively little effect on antimitotic activity against sea urchin eggs.
  • (15) 1-O-Hexadecyl-2-C,O-dimethyl-rac-glycero-3-phosphocholine (2-methyl-2-methoxy PAF) was prepared in a synthetic scheme beginning with the etherification of 2-methylpropen-1-ol.
  • (16) Modifications in the structure of isoalloxazine ring, etherification of OH-groups in the lateral D-ribityl chain, and the introduction of volume substitutors (N-piperidyl, D-ribitylamine, hydroxyethylamine) prevented the interaction of the analogue with riboflavin kinase.
  • (17) 5'-O-alkyl cytidines and uridines, resistant to catabolic enzymes, were as effective as the natural inducers cytidine and uridine; but etherification of one of the cis 2' or 3'hydroxyls fully abolished activity, pointing to a requirement of an intact ribose cis-glycol system for activity.
  • (18) The synthesis of 3-chloro-4-cyclopropylmethoxyphenylacetic acid (I) from 3-chloro-4-hydroxyacetophenone (III) by the etherification with cyclopropylmethyl bromide and by the Willgerodt reaction is described.
  • (19) Further reactions, such as hydrolysis, etherification and chromic oxidation, afforded many differently substituted [16,15-c]-pyrazoles of the estradiol and estrone series.
  • (20) Data on Liquid Gas Chromatographic method for detection of the acetic acid after etherification in the cadaveric organs are presented.

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